Melt the bittersweet chocolate and butter in a bowl for 2 minutes in microwave. Take out after 1 minute and stir.
Remove and stir in the cocoa powder and sugar .
Place chocolate mix in mixer bowl and whisk in the vanilla extract and eggs, one at a time, beating well after each addition.
Finally, stir in the flour, salt and semi-sweet chocolate chips
Pour into the prepared pan and bake for about 25-30 minutes, or until a toothpick inserted in the center comes out with a little batter and a few moist clumps clinging to it.
Turn oven to broil.
Sprinkle marshmallow pieces over top of brownies. Place back in oven on top rack for 1 minutes.
Watch through oven window, as soon as marshmallows start to brown remove from oven and let cool on a wire rack.